Materials

Oxide bonded silicon carbide:
molten aluminum runs off, cast iron gets replaced

OXYTRON from Blasch, silicon carbide in an oxide bond, for auto ladles, heater tubes, nozzles and parts that used to be cast iron.

A ladle that never needs a release layer, an insert that weighs a third of the iron one.
Both come from the same material.

Rotary degasser parts, porous plugs and lances
In short

Oxide bonded silicon carbide is non wetting in molten aluminum because the melt meets a surface of silicon carbide grains in an oxide bond of alumina and silica, which aluminum wets poorly at casting temperatures and does not react with the way it reacts with iron. Blasch OXYTRON is completely non wetting in molten aluminum without any surface treatment, so ladles and heater tubes stay free of buildup. The same grade replaces cast iron in wear parts at one third of the weight.

What oxide bonded silicon carbide is

Oxide bonded silicon carbide is silicon carbide whose grains are held together by an oxide phase, mostly alumina with some silica. The SiC grains bring hardness, thermal conductivity and wear resistance, the oxide bond brings oxidation resistance and a surface that molten metal does not grip.

OXYTRON is the Blasch grade: 67% SiC, 30% alumina and 3.7% silica, cast net shape with good dimensional tolerance and a smoother surface than cast iron. How the Blasch process works

Why it is non wetting in aluminum

Molten aluminum attacks iron and steel: it wets the surface, dissolves iron and builds up oxide and intermetallic layers. That is why steel ladles and tools are coated, and why the coating has to be renewed during production.

Oxide ceramics behave differently. At casting temperatures, molten aluminum wets alumina based surfaces poorly and does not dissolve them. OXYTRON presents exactly such a surface: SiC grains embedded in an alumina and silica bond, with fine pores that the metal does not enter.

The result in production, as Blasch reports it for its DuraLadle auto ladles: no protective layer is needed, ever, aluminum buildup and oxide formation drop, and a ladle runs for months without maintenance.

OXYTRON key properties

Values from the Blasch OXYTRON product information sheet.

Property OXYTRON
Composition 67% SiC, 30% Al2O3, 3.7% SiO2
Apparent porosity 14%
Modulus of rupture at 2,000 °F 8,000 psi (55 MPa)
Thermal conductivity 64 BTU·in/hr·ft²·°F

The modulus of rupture is measured at 2,000 °F, not at room temperature, which matters for parts that work hot. OXYTRON is also oxidation resistant and tolerates thermal shock.

The first step away from cast iron

Cast iron wears, corrodes and picks up aluminum; OXYTRON is where most plants start when they stop replacing metal with metal.

Blasch parts made from OXYTRON

Parts for molten aluminum and for wear parts that used to be metal.

DuraLadle auto ladle

Auto ladles for high pressure die casting from 5 to 50 lb, no release layer needed.

DuraLadle auto ladle

Immersion heater tubes

Heater sheaths for molten aluminum with long campaigns and less dross buildup.

Immersion heater tubes

Air heater inserts

Thin wall inserts that protect air preheater tube ends from fly ash erosion.

Air heater inserts

Dust collector components

SiClone multicyclone parts that replace cast iron at one third of the weight.

Dust collector components

More OXYTRON parts

OXYTRON is also used for FGD and spray nozzles, thermocouple protection tubes, abrasion resistant valves and fluidized bed nozzles. For aluminum degassing, Blasch uses a silicon carbide and alumina composite with a non wetting addition; the background is in Improved Ceramic Material for Aluminum Degassing.

OXYTRON parts go to molten metal plants and power generation. Its newer generation OXYTRON 015XDII adds a continuous silicon carbide phase for more erosion resistance, and for the highest temperatures and chemical attack there is sintered silicon carbide.

Sources

OXYTRON values and uses: Blasch OXYTRON product information sheet and material page; DuraLadle product sheet; Blasch power generation presentation. Wetting of oxide ceramics by molten aluminum: N. Eustathopoulos, M. G. Nicholas, B. Drevet, Wettability at High Temperatures, Pergamon, 1999.

Frequently asked

Questions about oxide bonded silicon carbide

Does OXYTRON need a coating in molten aluminum?

No. OXYTRON is non wetting in molten aluminum on its own, which is why DuraLadle auto ladles need no release layer at all.

Can OXYTRON replace a cast iron part?

Often yes, and it is the usual first step. It weighs about one third of cast iron, has a smoother surface and holds tighter tolerances.

Is OXYTRON used in other metals?

Yes. Together with NITRON it is used in copper and aluminum alloys for its non wetting behavior and thermal shock resistance.

What is the difference between OXYTRON and 015XDII?

015XDII is the newer generation, with a continuous silicon carbide phase that raises erosion resistance while keeping the non wetting behavior.

Aluminum sticking to your ladles
or heater tubes?

Send the part, the alloy and the cycle. A Blasch engineer checks whether OXYTRON can replace the coated metal part.

Talk to an engineer Call