About the article
| Item |
Detail |
| Title |
Improved Ceramic Material for Aluminium Degassing |
| Publication |
Simple Solutions, section Systems Integration, an online publication for metalcasting and die casting in North and South America, in English and Spanish |
| Year |
2017 |
| Author |
Philip Geers, Molten Metal Market Manager, Blasch Precision Ceramics |
Why aluminum needs degassing
Hydrogen dissolves readily in molten aluminum, and its solubility depends on temperature and pressure. Moisture in the air reacts with the melt surface, and alloying elements such as magnesium make it easier for hydrogen to enter. On solidification the hydrogen leaves solution and forms pores and voids, which means lower part quality and more scrap.
Static and dynamic systems
Static systems sit in the floor of the vessel: porous plugs, also called spargers, and some lance types. They reach a large share of the melt from below, have no moving parts and suit larger vessels where a longer service life justifies the installation cost.
Dynamic systems use a rotor on a shaft driven from above. Gas runs down the shaft, which turns at 200 to 400 rpm, and leaves through or under a head shaped to shear the bubbles. They suit smaller vessels such as foundry crucibles that cannot be fitted with a bottom plug.
What limits the conventional parts
A conventional porous plug is a solid ceramic cone inside a metal shell, with pores of 50 to 100 microns. The shell adds cost and must be Inconel when chlorine is in the gas. The body gives no control of gas direction, the large pores make large initial bubbles, and gas has to flow constantly to keep metal out of the pores.
Rotary shafts and heads have long been graphite, which machines easily but oxidizes at the metal and air interface, and multi hole heads plug when idle. Silica parts do not oxidize, but they react with aluminum and form dross.
What the finer ceramic changes
The Blasch process produces ceramic bodies with a continuous pore network and pores around 5 microns, with adjustable permeability and non wetting additives. In the article, a silicon carbide and alumina composite with these pores is proposed for both approaches:
- For plugs: many more small bubbles at the same gas flow, lower idle gas flow, and a better chance of survival if gas flow stops. Threads cast into the ceramic and internal voids that steer gas to the top can make the metal shell unnecessary.
- For rotors: a shaft with roughly 250% of the strength of silica, no oxidation at the surface of the melt, no major dross, and heads that release small bubbles in a controlled way.