Materials

Silicon nitride ceramic:
strength, toughness and heat transfer in one part

SINTRON silicon nitride from Blasch for molten metal, wear and parts that have to pass heat through their wall.

A dense, tough ceramic that conducts heat and does not wet in nonferrous melts.
Cast to shape, without the tooling charges of pressed parts.

Ceramic riser tubes for low pressure die casting
In short

Silicon nitride ceramic (Si3N4) is the best choice where a part needs high strength and fracture toughness together with thermal shock resistance, for example a heater tube, a thermocouple sheath or a riser tube in molten aluminum. It does not wet in nonferrous melts and conducts heat well enough to pass heat through its wall. Blasch SINTRON silicon nitride has a flexural strength of 830 MPa and a fracture toughness of 6.1 MPa·m½, and is rated for 1,000 °C without load.

What silicon nitride is

Silicon nitride is a compound of silicon and nitrogen. Its elongated grains interlock like fibers, which gives it more toughness than most other technical ceramics and lets it take thermal shock that would crack a dense alumina part.

There are several ways to make it: reaction bonded, hot pressed, sintered and sintered reaction bonded silicon nitride. They differ in density and strength, and in how complex a shape can be.

SINTRON is the Blasch silicon nitride. It is fully dense and can be formed into relatively complex shapes with good tolerance control, without the hard tooling setup charges that pressed parts carry.

SINTRON key properties

Values from the Blasch SINTRON product information sheet.

Property SI/metric Imperial
Density 3.29 g/cm³ 205.4 lb/ft³
Porosity 0% 0%
Color black
Flexural strength 830 MPa 120,400 psi
Hardness 1,580 kg/mm²
Fracture toughness KIC 6.1 MPa·m½
Poisson's ratio 0.27 0.27
Maximum use temperature, no load 1,000 °C 1,830 °F
Thermal conductivity 30 W/m·K 208 BTU·in/ft²·hr·°F
Coefficient of thermal expansion 3.3 x 10⁻⁶ /°C 1.8 x 10⁻⁶ /°F

The low thermal expansion and the thermal conductivity together explain its thermal shock behavior: the part heats more evenly and grows less, so less stress builds up between its hot and cold side.

The tough ceramic

Silicon nitride is the ceramic you choose when a part has to be thin, conduct heat and still take a knock when the crew changes it out on a hot furnace.

Where silicon nitride is the best choice

Molten aluminum and other nonferrous alloys: SINTRON is nonwetting to molten nonferrous alloys. Heater tubes and thermocouple sheaths stay free of buildup longer, and the reading or the heat transfer stays stable.

Thin walls that must transfer heat: immersion heater tubes protect the element or burner while passing its heat into the melt. A thin, strong, conductive wall does that job better than a thick refractory tube.

Wear with impact: in valves and wear components, the toughness of silicon nitride helps where a harder but more brittle ceramic would chip.

Where it is not the first choice: Blasch rates SINTRON for 1,000 °C without load, so very hot structural parts belong in sintered silicon carbide or an oxide refractory. For large wear shapes where cost per pound matters, a bonded silicon carbide grade is usually the economical answer.

Blasch parts made from silicon nitride

Parts for molten metal handling and wear.

Immersion heater tubes

Heater sheaths for aluminum and zinc that transfer heat and resist dross buildup.

Immersion heater tubes

Thermocouple protection tubes

Sheaths that give fast, stable readings in molten metal and hot gas.

Thermocouple protection tubes

Riser tubes

Tubes for low pressure die casting of aluminum.

Riser tubes for die casting

Abrasion resistant valves

Valve components where solids slide and impact.

Ceramic valve components

Related materials

For the same aluminum applications, Blasch also offers non wetting oxide bonded silicon carbide and aluminum titanate. Most silicon nitride parts go to molten metal plants and to chemical processing.

Sources

SINTRON values: Blasch SINTRON silicon nitride product information sheet. Product use: Blasch immersion heater tube and riser tube product pages. Types and microstructure of silicon nitride: W. D. Kingery, H. K. Bowen, D. R. Uhlmann, Introduction to Ceramics, 2nd ed., Wiley, 1976.

Frequently asked

Questions about silicon nitride

Is silicon nitride a ceramic?

Yes. Silicon nitride is a non oxide technical ceramic, known for combining strength, toughness and thermal shock resistance.

What are the disadvantages of silicon nitride?

It costs more than bonded silicon carbide or oxide refractories, and the Blasch grade is rated for 1,000 °C without load, lower than some silicon carbides.

Is silicon nitride harder than silicon carbide?

No. Silicon carbide is harder; silicon nitride is tougher.

What is silicon nitride used for in molten aluminum?

Heater tubes, thermocouple sheaths and riser tubes, because it does not wet in the melt and handles thermal shock.

A part that has to be thin
and tough?

Send the dimensions, the melt or medium and the temperature. A Blasch engineer checks whether silicon nitride or another grade fits better.

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